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Granular Formulations - Many aquatic herbicides are
used as dry granules of various sizes. Kinds available
are:
• Granulated pure chemical, such as crystalline
copper sulfate
• Granules or larger-size pellets of clay and other
materials impregnated with active ingredients
• Slow-release granules or pellets designed to release
the active ingredient in small amounts over an
extended period of time in the water.
Solutions -- Many herbicides come in solid forms
(such as copper sulfate) or liquid forms that readily
dissolve in water to form solutions. Solutions are stable
in that the chemical material doesn’t normally settle
out readily over a period of time. When using a
solution, fill the tank one-half full of water. Add the
chemical slowly, and stir until completely dissolved.
Next, bring the tank up to capacity. It may be
necessary to add a surfactant, a soap-like material that
tends to spread the water-soluble spray on the waxy
leaves of emergent or floating vegetation. When
applied under water, solutions disperse evenly and
bathe submerged plants completely.
Suspensions -- A suspension is formulated by mixing
a water-dispersible powder in water. This powder
doesn’t dissolve but is mixed or contained in the water.
Continuous agitation is needed in order to maintain the
material in suspension. There are two methods for
mixing: (1) Add the powder to a tank containing water
in which vigorous agitation is taking place. Never add
the powder to an empty tank, and never add powder to
a tank containing water in which there is little or no
agitation. If this is done, the powder will settle on the
bottom and possibly damage or clog the sprayer and
the sprayer lines. It will also form caked material on
the tank bottom. (2) A better way to mix dispersible
powders is to make a thin water slurry of the required
amount of material in a bucket or other container.
Thoroughly mix the wettable powder in the water
before adding it to the tank. Fill the tank one-half full
of water, pour the slurry into the tank, and thoroughly
agitate the water. When using suspensions, a sprayer
with mechanical agitation is preferable to one having
hydraulic agitation, because constant, vigorous mixing
is needed in order to maintain the suspension.
Emulsions -- An emulsion is a preparation that
doesn’t truly dissolve in the solvent or carrier, but
rather is dispersed throughout the carrier as almost
microscopic globules barely visible to the eye. Unlike a
true solution, if emulsions are given time; they will
separate or settle out of the carrier. When preparing
emulsions, if additional oil is needed, it should be
added to the chemical first. Then add the oil-chemical
mixture to a tank one-third full of water, and agitate as
the tank is filled to capacity. For best results with an
emulsion, constant agitation is needed. Most emulsions
consist of oil globules surrounded by water. Invert
emulsions are usually viscous and harder to apply;
however, they settle or sink more rapidly, reduce drift,
and adhere to plant surfaces.
"Bivert" or Invert Spray System -- The "bivert"
system is a relatively new system of applying chemical
spray. The system may be defined as a double invert. A
simple invert usually produces spray droplets of oil
surrounded by water or water drops surrounded by oil.
The "bivert" is a system with oil in water in oil. That
is, each spray droplet should have an oil center, an
outer layer of water, and a third layer of oil. The
herbicide may be included in either the oil, water, or in
both the oil and water phases. The "bivert" system,
along with simple inverts, has been used in the past to
treat terrestrial or floating plants, but it may have a
greater potential for aquatic weed control as a
technique for chemical application to submerged
plants.
The "bivert" spray enters below the water surface as
small, almost microscopic, droplets with the
consistency and adhesive texture of mayonnaise. It
descends through the water column, lands on and
adheres to the submerged vegetation, releasing the
herbicides close to the plants. Preliminary results of
this system indicate it has definite advantages over
parts-per-million treatment in several ways: it’s less
expensive, less chemical is needed, the chemical is
released near the plant, and the clinging property of the
droplet makes treatment in moving waters feasible.
Several herbicides are compatible to the system; others
must be specifically formulated to invert, or a specific
invert-additive must be mixed in the formulation.
The system has one distinct drawback. Since it’s a
form of invert, the mixing and application must be
done with extreme care. All chemical components
must be measured accurately, and the pressure and
vacuum hoses on the invert machinery must be
securely attached and airtight. Inverts are usually
lighter than water and must be weighted using an inert
material (sugar or molasses).